Over on cable, Discovery Channel has the first season finale of Turn & Burn and HBO has the documentary premiere of Valentine Road.
How I Met Your Mother (CBS): New. Barney has to work through some things with Ted. Lily realizes something. Runs 30 minutes.
Sleepy Hollow (FOX): New. Abbie’s sister has escaped from the psychiatric hospital, so Ichabod helps Abbie with the search. Ichabod and Abbie find out more about the evil they are dealing with.
Castle (ABC): New. Agents Beckett and McCord come to New York to investigate a case that Castle and the guys are working on already. Tensions arise while looking into the death of a former child star. Starts a minute after the hour and runs 59 minutes.
Hart of Dixie (The CW): Season Premiere. Zoe has spent the summer in New York and is thinking about just moving back permanently, but needs to go back to BlueBell one more time before she does. Brick wants Zoe to track down George. Lemon tries to help Wade save face.
Mom (CBS): New. Christy goes out on her first date since she got sober and things go just about how you would expect. Starts at the half hour after 2 Broke Girls and runs 30 minutes.
The Blacklist (NBC): New. The FBI begins searching for a Chinese spy that Red says hired him to get a classified CIA message decoded. Liz begins to look more into Tom. Starts a minute after the hour and runs 59 minutes.
Castle (TNT): Six episodes tonight.
Criminal Minds (ION): Has 11 episodes.
CSI: Miami (WE tv): Five episodes tonight.
Diners, Drive-Ins & Dives (Food Network): Has 12 episodes tonight.
Martin (TV One): Has 12 episodes early.
NCIS… (USA Network): Has 14 episodes.
Touched by an Angel (UPtv): Five episodes tonight.